Single-crystal films could advance solar cells

Amorphous silicon, deposited on a porous template fills the empty spaces. Laser
Amorphous silicon, deposited on a porous template fills the empty spaces. Laser heating melts the deposit and the top few microns of the silicon substrate. In a few nanoseconds the melted silicon recrystallizes. The substrate acts as a seed crystal for the material above, causing it to crystallize with the same alignment. This makes it easier for electric charges to flow, making possible more efficient solar cells and batteries.
Cornell researchers have developed a new method to create a patterned single-crystal thin film of semiconductor material that could lead to more efficient photovoltaic cells and batteries. The "holy grail" for such applications has been to create on a silicon base, or substrate, a film with a 3-D structure at the nanoscale, with the crystal lattice of the film aligned in the same direction (epitaxially) as in the substrate. Doing so is the culmination of years of research by Uli Wiesner, professor of materials science and engineering, into using polymer chemistry to create nanoscale self-assembling structures. He and his colleagues report the breakthrough in the Oct. 8 issue of the journal Science. They used the new method to create a film with a raised texture, made up of tiny pillars just a few nanometers across. "Just the ability to make a single-crystal nanostructure has a lot of promise," Wiesner said.
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