Metallic nanoparticles capable of adopting chirality patterns through their surface

Publication of the LCH in the journal ACS nano on January 7, 2022. CNRS-INC communication on February 15, 2022. Chiral plasmonic nanomaterials exhibiting intense optical activity are promising for numerous applications. In order to prepare those nanostructures, one strategy is to grow metallic nanoparticles in the presence of chiral molecules. However, in such approach the origin of the observed chirality remains uncertain. In this work, we expand the range of available chiral plasmonic nanostructures and we propose another vision of the origin of chirality in such colloidal systems. For that purpose, we investigated the synthesis of two core-shell Au@Ag and Au@Au systems built from gold nanobipyramid cores, in the presence of cysteine.