Oxygen ’holes’ could hold the key to higher performing EV batteries

Scientists have made a breakthrough in understanding and overcoming the challenges associated with nickel-rich materials used in lithium-ion batteries. This will enhance the stability and longevity of these lithium-ion batteries, paving the way for more efficient and reliable energy storage systems Annalena Genreith-Schriever Nickel is already used in lithium-ion batteries, but increasing the proportion of nickel could significantly improve battery energy density, making them especially suitable for electric vehicles and grid-scale storage. However, practical applications for these materials have been limited by structural instability and the tendency to lose oxygen atoms, which cause battery degradation and failure. The researchers, led by the University of Cambridge and the University of Birmingham, found that -oxygen hole- formation - where an oxygen ion loses an electron - plays a crucial role in the degradation of nickel-rich battery materials. These oxygen holes accelerate the release of oxygen that can further degrade the battery's cathode, one of its two electrodes. Their results are reported in the journal Joule. Using a set of computational techniques on UK regional supercomputers, the researchers examined the behaviour of nickel-rich cathodes as they charged.