Researchers unravel the complex reaction pathways in zero carbon fuel synthesis

Researchers have used isotopes of carbon to trace how carbon dioxide emissions could be converted into low-carbon fuels and chemicals. The result could help the chemical industry, which is the third largest subsector in terms of direct CO2 emissions, recycle its own waste using current manufacturing processes. When the eCO2EP: A chemical energy storage technology project started in 2018, the objective was to develop ways of converting carbon dioxide emitted as part of industrial processes into useful compounds, a process known as electrochemical CO2 reduction (eCO2R) While eCO2R is not a new technique, the challenge has always been the inability to control the end products. Now, researchers from the University of Cambridge have outlined how carbon isotopes can be used to trace intermediates during the process, which will allow scientists to create more selective catalysts, control product selectivity, and promote eCO2R as a more promising production method for chemicals and fuels in the low-carbon economy. Their results are reported in the journal Nature Catalysis . The project was led by Professor Alexei Lapkin, from Cambridge's Centre for Advanced Research and Education in Singapore (CARES Ltd) and Professor Joel Ager, from the Berkeley Education Alliance for Research in Singapore (BEARS Ltd) . Both organisations are part of the Campus for Research Excellence and Technological Enterprise (CREATE) funded by Singapore's National Research Foundation.